{"id":145385,"date":"2026-07-01T08:56:57","date_gmt":"2026-07-01T00:56:57","guid":{"rendered":"https:\/\/www.curtin.edu.au\/research\/?post_type=hdr-r-projects&p=145385"},"modified":"2026-07-01T08:56:57","modified_gmt":"2026-07-01T00:56:57","slug":"design-and-synthesis-of-tailored-phosphorus-and-diglycolamide-based-extract-ants-with-enhanced-steric-and-electronic-selectivity-for-critical-minerals","status":"publish","type":"hdr-r-projects","link":"https:\/\/www.curtin.edu.au\/research\/hdr-r-projects\/design-and-synthesis-of-tailored-phosphorus-and-diglycolamide-based-extract-ants-with-enhanced-steric-and-electronic-selectivity-for-critical-minerals\/","title":{"rendered":"Design and synthesis of tailored phosphorus and diglycolamide-based extract ants with enhanced steric and electronic selectivity for critical minerals"},"content":{"rendered":"\n
\n
\"\"<\/figure>\n\n\n\n

Critical minerals, especially rare earth elements (REEs), are indispensable to modern technologies, including renewable energy systems, electronics, and the defence sector. However, due to their chemical similarities, the separation of individual REEs remains a significant challenge. Conventional extractants often lack the required selectivity, resulting in inefficient and energy-intensive separation processes. CSIRO is a scientific partner in the project and the selected candidate may conduct the hydrometallurgy-related research components of the project at their facilities.<\/p>\n\n\n\n

Aim  <\/p>\n\n\n\n

Phosphorus-based extractants (e.g., phosphine oxides, phosphonates, phosphoramides) and diglycolamides (DGAs) have demonstrated strong affinity for REE ions and offer rich structural flexibility. By strategically introducing steric hindrance and electronic modifications, these ligands can be fine-tuned to enhance selectivity and extraction efficiency. This project aims to explore and develop novel phosphorus- and DGA-based ligands through rational molecular design, synthesis, and evaluation.<\/p>\n\n\n\n

Objectives <\/p>\n\n\n\n